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Waterborne Polyurethane/Acrylics Interpenetrating Networks Polymer:Preparation,Characterization and Application for antipilling coating materials

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DOI: 10.23977/jmpd.2017.11001 | Downloads: 97 | Views: 6732


Ren Yan 1,2, Zhangjian Fei 1, Dingchang Bo 2, Chen Jun 2


1 College of Textile, Tianjin Polytechnic University, 300387 Tianjin , China
2 College of Textile and Material , Xi′ an Polytechnic University, 710048 Xi′ an , Shannxi, China

Corresponding Author

Ren Yan


Aqueous polyurethane dispersions with C=C double bonds were synthesized by using Isophorone diisocyanate, Polyether diol 218, polyether-tribasic alcohol 310 and dimethylolbutanoic acid without any organic solvents. Then waterborne polyurethane-acrylic hybrid emulsion interpenetrating network were prepared with the method of pre-emulsification semi-continuous. Based upon the FT-IR, DSC, TG and particle size analysis, the experimental results showed that polyurethane with C=C double bond and acrylate has good compatibility and exhibits phase separation morphology with interpenetrating networks. Thermal stability and emulsion stability is good. Anti-pilling grade of different fabrics rise two or three levels after finishing by using waterborne polyurethane and acrylic ester interpenetrating networks polymer.


Waterborne polyurethane, acrylics, interpenetrating networks, anti-pilling,solvent-/emulsifier-free method.


Ren, Y. , Zhangjian, F. , Dingchang, B. and Chen, J. Waterborne Polyurethane/Acrylics Interpenetrating Networks Polymer:Preparation,Characterization and Application for antipilling coating materials. Journal of Materials, Processing and Design (2017) 1: 1-9. 


[1] Sundar S, Kannan T, Ganga R. Aqueous Di spersion of Polyurethane Poly-acrylic Acid Multiblock Copolymers Through Living Radical Polymerization [J]. Journal of Applied Polymer Science, 2013, 87(6) :1109-1115.
[2] Hegedus C R, Kloiber K A. Aqueous Acrylic-Polyurethane Hybrid Dispersions and  their Use in Industrial Coatings [J].Journal of Coatings Technology, 2006, 68(860): 39-48.
[3] Kukanja D, Golob J,  Zupancic-Valant A and Krajnc M. The Structure and Properties  of Acrylic-Polvurethane Hybrid Emulsions and Comparison with Physical Blends [J].  Journal of Applied Polymer Science, 2010, 78(1) :67-80.
[4] Hirose M,  Zhou J H  and  Nagai  K. Prog. The Structure and Properties of    Acrylic-Polyurethane Hybrid Emulsions[J]. Progress in Organic Coating, 2000,   (38) :27-34.
[5] Kim Byung Kyu, Lee Jong-Cheol Waterborne polyurethane and their properties[J].Journal of Polymer Science Part A, Polymer Chemistry, 1996, 34(6):1095-l104.
[6]Felix Sahmitt, Andteas Wenning, John-Volker Weiss. Recent development in aqueous two-component polyurethane coating[J].Pogress in Organic Coatings.2010,(40):99-103.
[7] G.Chen and K.Chen.Hybridization of aqueous-based polymerthane with glycidyl  methacrylate copolymer[J]. Appl. Polym .Sci. 1999, 71, 6, 903.
[8] Hegedus, C.R. Kloiber,K.A. Acrylic-polyurethane aqueous dispersions:structure and  properties in industrial coatings[J]. 21st Waterborne, High-Solids and Powder Coatings  Symposium, New Orleans, 9-11 February, 1994.
[9] Muscato  M.R. and  Sundberg  D.C. Design  of  PMMA / PSt  with composite  structure [J]. Polym. Sci.: Part A: Polym. Chem.1991.329(5). 1021-1024.
[10] S.A. Chem, S.T. Lee. Charaterization development of core-shell structure particles for PSt/PMMA composite latex [J]. Macro molecules.1991.558(4).3340-3345.
[11] C.S. Chen, G.W. Poehlein.Polymerization in nonuniform latex particles distribution of free radicals [J]. Journal of Polymer Science, Part A: Polymer Chemistry. 2007, 25(4) :617-631. 
[12] Hirose M,  Zhou J H  and  Nagai K.Prog.  The Structure  and  Properties of  Acrylic - Polyurethane  Hybrid  Emulsions[J]. Progress in Organic Coating, 2010,  (38) :27-34.
[13] L. H. Sperling, T.W. Chiu and D.A.Thomas. Polymerization condition & development  of a core-shell morphology in PMMA/PSt latex particles[J]. Appliled  Polymer: Sci. 1973, 322(12).2443-2445.
[14] Hegedus C.R., Kloiber K.A. Aqueous acrylic-polyurethane hybrid dispersion and  their use in industrial [J]. Coat.Tech. 1996, 68, (860) :39.
[15] Hirose M, Kadowaki F, Zhou J H. The structure and properties of core-shell type  acrylic - polyurethane hybrid aqueous emulsions [J]. Progress in Organic Coatings,  1997, (31) :157-169.
[16] D.J.Williams.Morphology of the monomer polymer particle in styrene emulsion  Polymerization[J].  Journal of Polymer Science, 1970, 8(10) :2657.
[17] Shen H.R., El-Aasser M.S, Vanderhoff J.W. Synthesis of special morphology particles  with seeded polymerization[J]. Polym Sci:Part A, Polym.Chem.1990.78(1).629-653.

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