Waterborne Polyurethane/Acrylics Interpenetrating Networks Polymer:Preparation,Characterization and Application for antipilling coating materials
DOI: 10.23977/jmpd.2017.11001 | Downloads: 87 | Views: 6212
Ren Yan 1,2, Zhangjian Fei 1, Dingchang Bo 2, Chen Jun 2
1 College of Textile, Tianjin Polytechnic University, 300387 Tianjin , China
2 College of Textile and Material , Xi′ an Polytechnic University, 710048 Xi′ an , Shannxi, China
Corresponding AuthorRen Yan
Aqueous polyurethane dispersions with C=C double bonds were synthesized by using Isophorone diisocyanate, Polyether diol 218, polyether-tribasic alcohol 310 and dimethylolbutanoic acid without any organic solvents. Then waterborne polyurethane-acrylic hybrid emulsion interpenetrating network were prepared with the method of pre-emulsification semi-continuous. Based upon the FT-IR, DSC, TG and particle size analysis, the experimental results showed that polyurethane with C=C double bond and acrylate has good compatibility and exhibits phase separation morphology with interpenetrating networks. Thermal stability and emulsion stability is good. Anti-pilling grade of different fabrics rise two or three levels after finishing by using waterborne polyurethane and acrylic ester interpenetrating networks polymer.
KEYWORDSWaterborne polyurethane, acrylics, interpenetrating networks, anti-pilling,solvent-/emulsifier-free method.
CITE THIS PAPER
Ren, Y. , Zhangjian, F. , Dingchang, B. and Chen, J. Waterborne Polyurethane/Acrylics Interpenetrating Networks Polymer:Preparation,Characterization and Application for antipilling coating materials. Journal of Materials, Processing and Design (2017) 1: 1-9.
 Sundar S, Kannan T, Ganga R. Aqueous Di spersion of Polyurethane Poly-acrylic Acid Multiblock Copolymers Through Living Radical Polymerization [J]. Journal of Applied Polymer Science, 2013, 87(6) :1109-1115．
 Hegedus C R, Kloiber K A. Aqueous Acrylic-Polyurethane Hybrid Dispersions and their Use in Industrial Coatings [J]．Journal of Coatings Technology, 2006, 68(860)： 39-48．
 Kukanja D, Golob J, Zupancic-Valant A and Krajnc M. The Structure and Properties of Acrylic-Polvurethane Hybrid Emulsions and Comparison with Physical Blends [J]. Journal of Applied Polymer Science, 2010, 78(1) ：67-80．
 Hirose M, Zhou J H and Nagai K. Prog. The Structure and Properties of Acrylic-Polyurethane Hybrid Emulsions[J]. Progress in Organic Coating, 2000, (38) ：27-34．
 Kim Byung Kyu, Lee Jong-Cheol Waterborne polyurethane and their properties[J]．Journal of Polymer Science Part A, Polymer Chemistry, 1996, 34(6):1095-l104．
Felix Sahmitt, Andteas Wenning, John-Volker Weiss. Recent development in aqueous two-component polyurethane coating[J].Pogress in Organic Coatings.2010,(40):99-103.
 G.Chen and K.Chen.Hybridization of aqueous-based polymerthane with glycidyl methacrylate copolymer[J]. Appl. Polym .Sci. 1999, 71, 6, 903.
 Hegedus, C.R. Kloiber,K.A. Acrylic-polyurethane aqueous dispersions：structure and properties in industrial coatings[J]. 21st Waterborne, High-Solids and Powder Coatings Symposium, New Orleans, 9-11 February, 1994.
 Muscato M.R. and Sundberg D.C. Design of PMMA / PSt with composite structure [J]. Polym. Sci.: Part A: Polym. Chem.1991.329(5). 1021-1024.
 S.A. Chem, S.T. Lee. Charaterization development of core-shell structure particles for PSt/PMMA composite latex [J]. Macro molecules.1991.558(4).3340-3345.
 C.S. Chen, G.W. Poehlein.Polymerization in nonuniform latex particles distribution of free radicals [J]. Journal of Polymer Science, Part A: Polymer Chemistry. 2007, 25(4) ：617-631.
 Hirose M, Zhou J H and Nagai K.Prog. The Structure and Properties of Acrylic - Polyurethane Hybrid Emulsions[J]. Progress in Organic Coating, 2010, (38) ：27-34.
 L. H. Sperling, T.W. Chiu and D.A.Thomas. Polymerization condition & development of a core-shell morphology in PMMA/PSt latex particles[J]. Appliled Polymer: Sci. 1973, 322(12).2443-2445.
 Hegedus C.R., Kloiber K.A. Aqueous acrylic-polyurethane hybrid dispersion and their use in industrial [J]. Coat.Tech. 1996, 68, (860) ：39.
 Hirose M, Kadowaki F, Zhou J H. The structure and properties of core-shell type acrylic - polyurethane hybrid aqueous emulsions [J]. Progress in Organic Coatings, 1997, (31) ：157-169.
 D.J.Williams.Morphology of the monomer polymer particle in styrene emulsion Polymerization[J]. Journal of Polymer Science, 1970, 8(10) ：2657.
 Shen H.R., El-Aasser M.S, Vanderhoff J.W. Synthesis of special morphology particles with seeded polymerization[J]. Polym Sci:Part A, Polym.Chem.1990.78(1).629-653.