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Black titanium dioxide toward sustainable water purification: Fundamentals, structure engineering, and future perspectives

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DOI: 10.23977/erej.2026.100113 | Downloads: 5 | Views: 60

Author(s)

Zhenmin Ding 1

Affiliation(s)

1 Shanghai Institute of Measurement and Testing Technology Co., Ltd., Shanghai, 200233, China

Corresponding Author

Zhenmin Ding

ABSTRACT

Black titanium dioxide (TiO₂) has emerged as a promising visible-light-responsive photocatalyst for water purification owing to its defect-rich structure, which enhances light harvesting and charge separation. This review summarized recent advances in the structural characteristics, preparation strategies, photocatalytic mechanisms, and structure engineering of black TiO₂. Its applications in degrading conventional organic pollutants and emerging contaminants were highlighted, together with challenges associated with real wastewater treatment. Current limitations regarding defect stability, mechanistic understanding, catalyst recovery, and performance evaluation were critically discussed. Finally, future perspectives, including precise defect engineering, operando characterization, data-driven catalyst design, and continuous-flow photocatalytic systems, were proposed to facilitate the practical application of black TiO₂ in sustainable water purification.

KEYWORDS

Black TiO₂; Defect engineering; Photocatalysis; Organic pollutants; Water purification

CITE THIS PAPER

Zhenmin Ding. Black titanium dioxide toward sustainable water purification: Fundamentals, structure engineering, and future perspectives. Environment, Resource and Ecology Journal (2026). Vol. 10, No.1, 99-108. DOI: http://dx.doi.org/10.23977/erej.2026.100113.

REFERENCES

[1] LI N., WANG R., ZHAO J., PENG X., PENG W., YAN B., CHEN G. (2026) In situ carbon recovery from refractory organics in wastewater: A critical review. Green Chemistry, 28 (21), 8649–8666.
[2] TAWFIK A., ALALM M., AWAD H., ISLAM M., QYYUM M., AL-MUHTASEB A., OSMAN A., LEE M. (2022) Solar photo-oxidation of recalcitrant industrial wastewater: A review. Environmental Chemistry Letters, 20, 1839–1862.
[3] HU Y., YANG H., CHENG W., CHANG F., HU J., WANG M., XU Q., XU Y. (2025) Preparation and adsorption performance of Artemisia argyi biochar. Journal of Liaocheng University (Natural Science Edition), 38(6), 891-899
[4] ARORA N., MISHRA I. (2022) Sustainable development goal 6: Global Water Security. Environmental Sustainability, 5, 271–275.
[5] VLACHOPOULOU M., COUGHLIN D., FORROW D., KIRK S., LOGAN P., VOULVOULIS N. (2014) The potential of using the Ecosystem Approach in the implementation of the EU Water Framework Directive. Science of The Total Environment, 470–471, 684–694.
[6] Thuan D., Ngo H., Thi H., Chu T. (2023) Photodegradation of hazardous organic pollutants using titanium oxides-based photocatalytic: A review. Environmental Research, 229, 116000.
[7] VARSHNEY G., KANEL S., KEMPISTY D., VARSHNEY V., AGRAWAL A., SAHLE-DEMESSIE E., VARMA R., NADAGOUDA M. (2016) Nanoscale TiO2 films and their application in remediation of organic pollutants. Coordination Chemistry Reviews, 306(1), 43–64.
[8] Augugliaro V., Bellardita M., Loddo V., Palmisano G., Palmisano L., Yurdakal S. (2012) Overview on oxidation mechanisms of organic compounds by TiO2 in heterogeneous photocatalysis. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 13(2), 224–245.
[9] KAUR B., SINGH P., THAKUR S., SINGH A., CHAUDHARY V., KUMAR N., KHAN A., RUB M., AZUM N., RAIZADA P. (2025) Harnessing 3D printing for tailored TiO₂ structures redefining organic pollutant degradation. Journal of Environmental Chemical Engineering, 13(2), 116042.
[10] CHEN X., LIU L., YU P., MAO S. (2011) Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science, 331(6018), 746–750.
[11] WANG, Z., YANG, C., LIN, T., YIN, H., CHEN, P., WAN, D., XU, F., HUANG, F., LIN, J., XIE, X. JIANG, M. (2013) H-Doped black titania with very high solar absorption and excellent photocatalysis enhanced by localized surface plasmon resonance. Advanced Functional Materials, 23, 5444-5450.
[12] ZHAO H., LIU L., ANDINO J., LI Y. (2013) Bicrystalline TiO2 with controllable anatase–brookite phase content for enhanced CO2 photoreduction to fuels. Journal of Materials Chemistry A, 1 (28), 8209–8216.
[13] TIAN M., LIU C., GE J., GEOHEGAN D., DUSCHER G., ERES G. (2019) Recent progress in characterization of the core–shell structure of black titania. Journal of Materials Research, 34(7), 1138–1153.
[14] ANDRONIC L., ENESCA A. (2020) Black TiO2 synthesis by chemical reduction methods for photocatalysis applications. Frontiers in Chemistry, 8, 565489.
[15] SAMBYAL S., Sudhaik A., SONU, RAIZADA P., SINGH A., NGUYEN V., KAYA S., KHAN A., SINGH P.,  ALZAHRANI K. (2025) Recent advancements in sustainable CO2 conversion utilizing black TiO2-based photocatalysts. Journal of Materials Science, 60, 14908–14937.
[16] KHORASHADIZADE E., RAHIMI K., MOHAJERNIA S., HEJAZI S., NASERI N., MORADLOU O., MOSHFEGH A., SCHMUKI P. (2024) Comparing plasma reduction and thermal hydrogenation in oxygen-deficient TiO2-x nanotubes for photoelectrochemical H2 production. International Journal of Hydrogen Energy, 74, 434–446.
[17] LIANG Y., HUANG G., XIN X., YAO Y., LI Y., YIN J., LI X., WU Y., GAO S. (2022) Black titanium dioxide nanomaterials for photocatalytic removal of pollutants: A review. Journal of Materials Science & Technology, 112, 239–262.
[18] IVANOVSKAYA M., CHERNYAKOVA K., OVODOK E., POZNYAK S., KOTSIKAU D., MICUSIK M. (2023) Synthesis and structural features of black TiO2 nanotubes after annealing in hydrogen. Materials Chemistry and Physics, 297, 127416. 
[19] FROLOVA E., KHOMYCH V., KRAVCHUK R., KOLOMYS O., GUDENKO Y., PYLYPCHUK O., STYOPKIN V., DOBROVOLSKIY A. (2023) Plasma treatment of titanium dioxide film for black TiO2. Problems of Atomic Science and Technology, 146, 180–183.
[20] RAJARAMAN T., PARIKH S., GANDHI V. (2020) Black TiO2: a review of its properties and conflicting trends. Chemical Engineering Journal, 389, 123918
[21] LI Z., WANG S.., WU J., ZHOU W. (2022) Recent progress in defective TiO2 photocatalysts for energy and environmental applications. Renewable and Sustainable Energy Reviews, 156, 111980.
[22] BAI W., CHANG F., LI K., KOU Y., Tian W. (2025) High-entropy materials for photocatalysis: A mini review. Catalysts, 15(12), 1152.
[23] GUETTAÏ N., AMAR H. (2005) Photocatalytic oxidation of methyl orange in presence of titanium dioxide in aqueous suspension. Part I: parametric study. Desalination, 185, 427–437.
[24] SARAFRAZ M., AMINI M., ADIBAN M., ESLAMI A. (2020) Facile synthesis of mesoporous black N–TiO2 photocatalyst for efficient charge separation and the visible-driven photocatalytic mechanism of ibuprofen degradation. Materials Science in Semiconductor Processing, 120, 105258.

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