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PREPARATION, AND UTILIZATION OF CHROMIUM METAL ORGANIC FRAMEWORK FOR CRUDE OIL REMEDIATION

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DOI: 10.23977/envcp.2022.010101 | Downloads: 29 | Views: 1659

Author(s)

Orodu Victor Enearepuadoh 1, Abasi Cyprian Yameso 1, Dikio Ezekiel Dixon 1

Affiliation(s)

1 Department of Chemical Sciences, Faculty of Science, Niger Delta University, Wilberforce Island, P.M.B 071, Amassoma, Bayelsa State. Nigeria

Corresponding Author

Orodu Victor Enearepuadoh

ABSTRACT

Chromium-metal organic framework (Cr-MOF) was synthesized by solvothermal method. It was characterized using Fourier Transform Infrared (FTIR) spectrometer, Scanning Electron Microscope and Energy Dispersive X-ray (EDX) Spectroscopy. Composites of Cr-MOF/Clay and Cr-MOF/charcoal were also prepared. The as-synthesized MOF and the composites were all applied for the adsorption of crude oil on water media. Characterization results showed the presence of unsaturated C=C, C=O vibrations as well as metal-oxygen and OH group vibrations which confirmed the formation of the Cr-MOF. EDX spectra also confirmed formation of the MOF with the observed peaks of Cr, C and O. Adsorption results showed the oil in water could be adsorbed by as-synthesized Cr-MOF, though very slight the adsorption of the crude oil increased almost linearly with an increase in adsorbent dose. Adsorption of crude oil by Cr-MOF ranged from 10 - 70% for various doses from 0.2-1.0 g. However, the adsorption of the crude oil was greatly enhanced in the Cr-MOF/charcoal composite, whose sorption ranged from 80-100%. The effect of pH tipped in the acid range and increased with adsorption in the alkaline region for the pHs considered.

KEYWORDS

Cr-MOF, Adsorption, Charcoal, Composite, Remediation

CITE THIS PAPER

Orodu Victor Enearepuadoh, Abasi Cyprian Yameso and Dikio Ezekiel Dixon, PREPARATION, AND UTILIZATION OF CHROMIUM METAL ORGANIC FRAMEWORK FOR CRUDE OIL REMEDIATION. Environment and Climate Protection (2022) Vol. 1: 1-12. DOI: http://dx.doi.org/10.23977/envcp.2022.010101.

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